亲金作用

左边的配体与三倍量的卤化亚金反应（每个三苯基膦基团与一个金原子配位），右侧的配合物中由于亲金作用而妨碍单键的自由旋转。破坏这种作用所需要的温度可用来衡量的亲金作用的强弱。[1]

在化学中，亲金作用（也称金键）是指金配合物通过金-金键形成多聚体的倾向。[1][2]

参考资料

  1. ^ 1.0 1.1 Hubert Schmidbaur. The Aurophilicity Phenomenon: A Decade of Experimental Findings, Theoretical Concepts and Emerging Application. Gold Bulletin. 2000, 33 (1): 3–10 [2011-06-02]. （原始内容存档于2016-04-27）. 
  2. ^ Hubert Schmidbaur. Ludwig Mond Lecture. High-carat gold compounds. Chem. Soc. Rev. 1995, 24: 391–400. doi:10.1039/CS9952400391. 
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